МОДИФИКАЦИЯЛАНҒАН ТАБИҒИ СОРБЕНТТЕРМЕН АҒЫНДЫ  СУЛАРДЫ ТАЗАЛАУ

Мырзабай Джетимов; Лаура Ыбраймжанова; Эльмира Камбарова; Айнур Игембаева; Курманкуль Абаева; Наурузбай Тажетдинов

doi:10.37884/4-2024/33

Abstract

This article presents the results of a study of the effectiveness of using natural mineral sorbents based on zeolite, bentonite clays and diatomite in the low mountains of Zhetysu (Dzungar) Alatau for purification and conditioning of drinking water and wastewater treatment from sulfates, bicarbonates, nitrates, heavy metal ions and other harmful impurities .

The physicochemical and mineralogical composition of natural sorbents and the adsorption efficiency of the resulting combined sorbents were studied, and an increase in sorption activity was found depending on the composition of the sorbent and the influence of modification of the sorbents on the firing temperature. To increase the adsorption capacity of sorbents during heat treatment, the mechanism of thermal activation was used, which is due to the removal of adsorbed and constitutional water, that is, an increase in total porosity. Close to thermal activation is the method of hydrothermal modification of natural sorbents - treatment in water vapor at high temperatures and pressure.

The scientific and practical value of our research is to obtain a modification of the sorbent for wastewater purification, with simultaneous sorption of chemical and microbiological contaminants contained in water, promoting disinfection and softening of water, increasing the degree of saturation of the treated water with calcium, magnesium salts and microelements, not requiring for use complex equipment. The technical result consists in creating a modified complex of natural adsorbents with the sorbing ability of chemical and microbiological contaminants, disinfecting and softening water, enriching it with calcium, magnesium, sodium, potassium ions, as well as microelements.

Experiments conducted on the use of natural mineral sorbents in water purification processes from contaminants have revealed significant differences in the effectiveness of the considered sorbents, determined by their mineral composition, microstructure, sorption capacity and the presence of catalytic activity.

zeolite, bentonite, diatomite, sorbents, adsorption, heavy metals.

01 Introduction

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02 References

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2. Алтынбеков Ф. Е. Гигиеническая оценка цеолитов закавказских месторождений, предлагаемых для совершенствования технологических схем обработки воды хозяйственнопитьевых водоисточников/Автореф. дисс. канд. мед. наук //Алматы.—1985.-21 с. – 1985.
3. Kaušpėdienė D. et al. Comparison of the efficiency of activated carbon and neutral polymeric adsorbent in removal of chromium complex dye from aqueous solutions //Journal of Hazardous Materials. – 2010. – Т. 179. – №. 1-3. – С. 933-939.
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5. Bhatnagar A., Sillanpää M. Utilization of agro-industrial and municipal waste materials as potential adsorbents for water treatment—a review //Chemical engineering journal. – 2010. – Т. 157. – №. 2-3. – С. 277-296.
6. Khan S. A. et al. Adsorption of chromium (III), chromium (VI) and silver (I) on bentonite //Waste Management. – 1995. – Т. 15. – №. 4. – С. 271-282.
7. M.Jetimov, E.Andasbayev, A.Sataeva Efficiency of using a complex of modified natural adsorbents for wastewater treatment. In the collection: The Europe and the Turkic World: Science, Engineering and Technology. Materials of the III International Scientific-Practical Conference. 2018. С. 447-452.
8. Жетимов М. А. и др. Значение комплексных природных адсорбентов, состоящих из цеолита, бентонита и диатомита, для очистки питьевых и сточных вод //Наука и образование: новое время. – 2019. – №. 1. – С. 24-28.
9. ЕспеноваМ.М., ЖапаркуловаЕ.Д., НусипбековМ.Ж. Агрохимическая характеристика сточных вод г. Талдыкоргана и возможности использования их для орошения // «Ізденістер, нəтижелер», №2 (74) 2017. - 192-198 стр.
10. БайжигитА., АнуарбековК.К., АлдияроваА.Е., ЗубаировО.З. Changes in the salt composition of the sierozem soils during watering with wastewater in the conditions of south Kazakhstan // «Ізденістер, нəтижелер», №1 (77) 2018. - 144-148 стр.
11. Doula M. K. Removal of Mn2+ ions from drinking water by using Clinoptilolite and a Clinoptilolite–Fe oxide system //Water research. – 2006. – Т. 40. – №. 17. – С. 3167-3176.
12. Xu H. Y. et al. Kinetic research on the sorption of aqueous lead by synthetic carbonate hydroxyapatite //Journal of Environmental Management. – 2008. – Т. 86. – №. 1. – С. 319-328.
13. Комарова Л.Ф. Физико-химические основы применения природных и модифицированных сорбентов в процессах очистки воды // Химия и технология воды- 1998. — Т. 20, № 1. С.42-51.
14. Wang S., Peng Y. Natural zeolites as effective adsorbents in water and wastewater treatment //Chemical engineering journal. – 2010. – Т. 156. – №. 1. – С. 11-24.
15. Harutyunyan L. R., Pirumyan G. P. Purification of waters from anionic and cationic surfactants by natural zeolites //Proceedings of the YSU B: Chemical and Biological Sciences. – 2015. – Т. 49. – №. 1 (236). – С. 21-28.
16. Bourliva A. et al. Municipal wastewater treatment with bentonite from Milos Island, Greece //Bulletin of the Geological Society of Greece. – 2010. – Т. 43. – №. 5. – С. 2532-2539.
17. Chatterjee T., Chatterjee S., Woo S. H. Enhanced coagulation of bentonite particles in water by a modified chitosan biopolymer //Chemical Engineering Journal. – 2009. – Т. 148. – №. 2-3. – С. 414-419.
18. Jetimov M. et al. Sorption characteristics of zeolite and bentonite natural adsorbents modified complex //News of the National Academy of Sciences of the Republic of Kazakhstan Series of Geology and Technical Sciences. – 2020. – Т. 4. – С. 138-146.

Citation Links

[1]2024. WASTEWATER TREATMENT WITH MODIFIED NATURAL SORBENTS. Izdenister natigeler. 4 (104) (Dec. 2024), 316–326. DOI:https://doi.org/10.37884/4-2024/33.

(1)WASTEWATER TREATMENT WITH MODIFIED NATURAL SORBENTS. Izdenister natigeler 2024, No. 4 (104), 316-326. https://doi.org/10.37884/4-2024/33.

WASTEWATER TREATMENT WITH MODIFIED NATURAL SORBENTS. (2024). Izdenister Natigeler, 4 (104), 316-326. https://doi.org/10.37884/4-2024/33

WASTEWATER TREATMENT WITH MODIFIED NATURAL SORBENTS. Izdenister natigeler, [S. l.], n. 4 (104), p. 316–326, 2024. DOI: 10.37884/4-2024/33. Disponível em: https://natsus.kaznaru.edu.kz/index.php/research/article/view/727. Acesso em: 15 sep. 2026.

“WASTEWATER TREATMENT WITH MODIFIED NATURAL SORBENTS”. 2024. Izdenister Natigeler, no. 4 (104) (December): 316-26. https://doi.org/10.37884/4-2024/33.

“WASTEWATER TREATMENT WITH MODIFIED NATURAL SORBENTS” (2024) Izdenister natigeler, (4 (104), pp. 316–326. doi:10.37884/4-2024/33.

[1]“WASTEWATER TREATMENT WITH MODIFIED NATURAL SORBENTS”, Izdenister natigeler, no. 4 (104), pp. 316–326, Dec. 2024, doi: 10.37884/4-2024/33.

“WASTEWATER TREATMENT WITH MODIFIED NATURAL SORBENTS”. Izdenister Natigeler, no. 4 (104), Dec. 2024, pp. 316-2, https://doi.org/10.37884/4-2024/33.

“WASTEWATER TREATMENT WITH MODIFIED NATURAL SORBENTS”. Izdenister natigeler, no. 4 (104) (December 30, 2024): 316–326. Accessed September 15, 2026. https://natsus.kaznaru.edu.kz/index.php/research/article/view/727.

1.WASTEWATER TREATMENT WITH MODIFIED NATURAL SORBENTS. Izdenister natigeler [Internet]. 2024 Dec. 30 [cited 2026 Sep. 15];(4 (104):316-2. Available from: https://natsus.kaznaru.edu.kz/index.php/research/article/view/727

1.WASTEWATER TREATMENT WITH MODIFIED NATURAL SORBENTS. Izdenister natigeler. 2024;(4 (104):316-326. doi:10.37884/4-2024/33

[1] 1. Kaya A., Ören A. H. Adsorption of zinc from aqueous solutions to bentonite //Journal of hazardous materials. – 2005. – Т. 125. – №. 1-3. – С. 183-189.

[2] 2. Алтынбеков Ф. Е. Гигиеническая оценка цеолитов закавказских месторождений, предлагаемых для совершенствования технологических схем обработки воды хозяйственнопитьевых водоисточников/Автореф. дисс. канд. мед. наук //Алматы.—1985.-21 с. – 1985.

[3] 3. Kaušpėdienė D. et al. Comparison of the efficiency of activated carbon and neutral polymeric adsorbent in removal of chromium complex dye from aqueous solutions //Journal of Hazardous Materials. – 2010. – Т. 179. – №. 1-3. – С. 933-939.

[4] 4. Ковалевского В.В. Об использовании углеродистых сорбентов на основе природных минеральных пород для очистки питьевых и сточных вод // Мат. конф. «Акватерра». — СПб. — 1999. С. 40.

[5] 5. Bhatnagar A., Sillanpää M. Utilization of agro-industrial and municipal waste materials as potential adsorbents for water treatment—a review //Chemical engineering journal. – 2010. – Т. 157. – №. 2-3. – С. 277-296.

[6] 6. Khan S. A. et al. Adsorption of chromium (III), chromium (VI) and silver (I) on bentonite //Waste Management. – 1995. – Т. 15. – №. 4. – С. 271-282.

[7] 7. M.Jetimov, E.Andasbayev, A.Sataeva Efficiency of using a complex of modified natural adsorbents for wastewater treatment. In the collection: The Europe and the Turkic World: Science, Engineering and Technology. Materials of the III International Scientific-Practical Conference. 2018. С. 447-452.

[8] 8. Жетимов М. А. и др. Значение комплексных природных адсорбентов, состоящих из цеолита, бентонита и диатомита, для очистки питьевых и сточных вод //Наука и образование: новое время. – 2019. – №. 1. – С. 24-28.

[9] 9. ЕспеноваМ.М., ЖапаркуловаЕ.Д., НусипбековМ.Ж. Агрохимическая характеристика сточных вод г. Талдыкоргана и возможности использования их для орошения // «Ізденістер, нəтижелер», №2 (74) 2017. - 192-198 стр.

[10] 10. БайжигитА., АнуарбековК.К., АлдияроваА.Е., ЗубаировО.З. Changes in the salt composition of the sierozem soils during watering with wastewater in the conditions of south Kazakhstan // «Ізденістер, нəтижелер», №1 (77) 2018. - 144-148 стр.

[11] 11. Doula M. K. Removal of Mn2+ ions from drinking water by using Clinoptilolite and a Clinoptilolite–Fe oxide system //Water research. – 2006. – Т. 40. – №. 17. – С. 3167-3176.

[12] 12. Xu H. Y. et al. Kinetic research on the sorption of aqueous lead by synthetic carbonate hydroxyapatite //Journal of Environmental Management. – 2008. – Т. 86. – №. 1. – С. 319-328.

[13] 13. Комарова Л.Ф. Физико-химические основы применения природных и модифицированных сорбентов в процессах очистки воды // Химия и технология воды- 1998. — Т. 20, № 1. С.42-51.

[14] 14. Wang S., Peng Y. Natural zeolites as effective adsorbents in water and wastewater treatment //Chemical engineering journal. – 2010. – Т. 156. – №. 1. – С. 11-24.

[15] 15. Harutyunyan L. R., Pirumyan G. P. Purification of waters from anionic and cationic surfactants by natural zeolites //Proceedings of the YSU B: Chemical and Biological Sciences. – 2015. – Т. 49. – №. 1 (236). – С. 21-28.

[16] 16. Bourliva A. et al. Municipal wastewater treatment with bentonite from Milos Island, Greece //Bulletin of the Geological Society of Greece. – 2010. – Т. 43. – №. 5. – С. 2532-2539.

[17] 17. Chatterjee T., Chatterjee S., Woo S. H. Enhanced coagulation of bentonite particles in water by a modified chitosan biopolymer //Chemical Engineering Journal. – 2009. – Т. 148. – №. 2-3. – С. 414-419.

[18] 18. Jetimov M. et al. Sorption characteristics of zeolite and bentonite natural adsorbents modified complex //News of the National Academy of Sciences of the Republic of Kazakhstan Series of Geology and Technical Sciences. – 2020. – Т. 4. – С. 138-146.